General Advice: Poison information centers in each state can provide additional assistance for scheduled poisons. Ensure that medical personnel and those providing first aid are aware of the material(s) involved and take precautions to protect themselves. Symptoms and Effects: Irritation, unconsciousness, visual disturbances, metabolic acidosis, drowsiness, dizziness, suffocation, shortness of breath, nervous system effects, cardiovascular effects, cough, nausea, vomiting, diarrhea, abdominal pain, constipation, blindness, and respiration effects. Harmful or fatal if swallowed, inhaled, or absorbed through the skin. Causes irritation to the eyes, skin, respiratory tract, and gastrointestinal tract. May cause blindness or visual disturbances if absorbed into the blood stream. May affect the blood, brain, urinary system, liver, spleen, eyes, kidneys, cardiovascular system, and pancreas. Prolonged or repeated exposure may cause damage to liver, kidneys, brain, cardiovascular system, central nervous system, blood, spleen, eyes, and heart. Prolonged or repeated exposure may also cause adverse reproductive effects, mutagenic effects, and dermatitis. Immediate Medical Care/ If you feel unwell or are concerned, call a poison center or doctor immediately. Special Treatment: Treat symptomatically. 5. FIREFIGHTING MEASURES Suitable Extinguishing Media: Water spray, dry powder, alcohol resistant foam, carbon dioxide. Unsuitable Extinguishing Media: Do not use a solid (straight) water stream, as it may scatter and spread fire. Hazardous Combustion Carbon oxides, nitrogen oxides. Products: Specific Hazards: Flammable. Vapors may cause flash fire or ignite explosively. Burns vigorously if ignited easily by heat, sparks, or flames. Material may burn with an invisible flame. Sealed containers may explode when heated or involved in fire. Material is sensitive to static discharge. Vapors may travel considerable distance to source of ignition and flash back. Vapor from the solvent may accumulate in container headspace, resulting in flammability hazard. Special Protective Equipment/ As in any fire, wear MSHA/NIOSH-approved (or equivalent), self-contained, positive- Precautions for Firefighters: pressure or pressure-demand breathing apparatus and full protective gear. Use water spray to cool unopened containers. Move containers from fire area, if you can do so without risk. This material may evaporate and leave a flammable residue if spilled. In the event of fire and/or explosion, do not breathe fumes. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions and Ventilate area of leak or spill. Isolate hazard area and keep unnecessary and unprotected Protective Equipment: personnel away from the area of the leak or spill. Keep upwind. Keep out of low areas. Wear appropriate personal protective equipment (see Section 8). Remove all sources of ignition. Pay attention to flashback. Take precautionary measures against static discharge. All equipment used when handling the product must be grounded. Use spark-proof tools and explosion-proof equipment. Avoid contact with eyes, skin, and clothing. Emergency Procedures: In case of chemical emergency, or if unsure how to address an accidental release, consult a professional (see Section 1). Methods for Containment: Eliminate all sources of ignition. Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements, or confined areas. Dike the spilled material where possible. Product should not be released to the environment. Contain and recover liquid when possible. Product: Sudan III Fecal Stain Revision Date: 10/10/2016 3/9
